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Check the text at the bottom of the page from N3NDJ, Dave Sarraf. Dave wrote me an excellent email detailing some of the problems with the device in the article and solutions to those problems. He also includes a little bit of history concerning thermo-electric devices.
Thanks Dave! vy 73 de NS8O
PAGE 2
Your web page notes mentioned materials for the wires. Use standard
thermocouple pairs such as Type K (chromel/alumel), Type T
(copper/constantan) or type J (....../???) . Once source is Omega
Industries in Stamford CT. Since you don't care about accuracy buy
extension quality wire rather than thermocouple quality wire becuase it
is less expensive.
I question twisting the wires together as shown in the encyclopedia
article. Every place that the wires touch creates a junction, so
current could flow in a loop between the hot junction and the nearest
twist rather than from the hot junction to the cold junctions at the far
ends of each wire. This would greatly reduce the already low output of
the device. Instead spread the wires so they don't touch. Soldering is
ok for the cold junction. Rosin flux will not be aggressive enough to
clean the chromel and alumel wires. The best way to bond the hot end
would be by spot welding. This creates a reliable joint without the
concern of the candle flame evaporating lead from the solder and
dispersing it into the air. Twisting would work for a quick test but
the wires would soon oxidize and make a bad connection.
Thermionic and thermoelecric converters are rather old devices. They
were studied extensively in the early 1960's but fell from fashion when
fuel cells began to improve. About every 15 years the idea is
resurrected and studied again using new materials or new geometries.
The major attraction of these converters is silent and passive operation
and the ability to utilize waste heat from combustion or other
processes. Their efficiency is not very high but in some situations the
advantages are too great to ignore. They have been used on some
spacecraft to convert decay heat from bricks of radioisotopes to
electricity. With no moving parts this power source is highly
reliable. Several organizations have used them to make electricity in
the field using either waste heat recovered from turbines or directly
heated by some source of external combustion. Such generators are
versatile, reliable, and nearly silent.
Most recently TPV is making inroads. TPV, or thermophotovoltaics, uses
photocells to convert heat to electricity. The source or emitter
operates between 900 and 1700 C. The light emitted by the source
(visible or infrared) falls on cells whose bandgap is tuned to the
incident wavelength. Systems having efficiencies comparable to internal
combustion or power plants have been demonstrated, and a few companies
are planning camp stove or lantern-type generators for the backpacker
industry. A few years ago JX Crystals demonstrated a miniature system
that powered a transistor radio from a candle flame and a larger system
that ran a portable TV set from a propane flame. A company in New
England was working toward a gas home furnace that used some of the heat
to make enough electricty to power pumps and blowers to make the furnace
completely self-powered.
All of this does have some applications to QRP. The encyclopedia
article shows that it is possible to power a radio from a candle, and if
changes were made I would expect that you may even power a transmitter.
A lesson to be learned form the TPV folks is that the efficiency of most
PV cells rises quickly if the light is concentrated. Try adding
reflectors to solar panels to increase their output. They also learned
that efficiency falls with rising temperature, so make sure that the
cells are well-cooled if you do try this. Do this by adding fins to the
back of the panel; a fan would most certainly be counterproductive.
Dave Sarraf
N3NDJ